Ness-
1)unlock in story mode
2)fight in 5 matches
Marth-
1)finish classic mode with any character
2)fight 10 matches
3)unlock in story mode
Luigi-
1)unlock in story mode
2)fight 22 matches
3)clear classic mode with no continues in any level
Falco-
1)unlock in story mode
2)finish the 100 man brawl
3)fight 50 matches
Captain Flacon-
1)unlock in story mode
2)clear classic mode under 12 minutes
3)fight 70 matches
Lucario-
1)unlock in stroy mode
2)complete 5 target tests
3)fight 100 matches
Snake-
1)play on shadow moses island 15 times
2)unlock in story mode
3)fight 130 matches
R.O.B-
1)collect 250 trophies
2)unlock in story mode
3)fight 160 matches
Ganondorf-
1)finish classic mode with Zelda or Link
2)unlock in story mode
3)fight 200 matches
Mr. game and Watch-
1)complete 30 target tests with any character
2)unlock in story mode
3)fight 250 matches
Sonic-
1)clear classic mode with 10 dfinish ifferent charatcters
2)play for a total of 10 hours
3)unlock in story mode
4)fight 300 matches
Jigglypuff-
1)compete classic mode with any character
2)finish event #20
3)unlock in story mode
4)fight 350 matches
Toon Link-
1)finish the story mode and then finish the classic mode
2)fight 400 matches
Wolf-
1)finish story mode then complete boss battles with fox or falco
2)fight in 450 matches
1)finish classic mode with any character